C1ee01889b 4230..4238

Hydrogen electro-oxidation kinetics at the Pt | CsH2PO4 interface have been evaluated. Thin films of nanocrystalline platinum 7.5–375 nm thick and 1–19 mm in diameter were sputtered atop polycrystalline discs of the proton-conducting electrolyte, CsH2PO4, by shadow-masking. The resulting Pt | CsH2PO4 | Pt symmetric cells were studied under uniform H2-H2O-Ar atmospheres at temperatures of 225–250 C using AC impedance spectroscopy. For thick platinum films (>50 nm), electro-oxidation of hydrogen was found to be limited by diffusion of hydrogen through the film, whereas for thinner films, diffusion limitations are relaxed and interfacial effects become increasingly dominant. Extrapolation to vanishing film thickness implies an ultimate interfacial resistivity of 2.2 U cm, likely reflecting a process at the Pt | H2(g) interface. Films 7.5 nm in thickness displayed a total electrooxidation resistivity, ~ R, of 3.1 U cm, approaching that of Pt-based composite anodes for solid acid fuel cells (1–2 U cm). In contrast, the Pt utilization ( ~ R /Pt loading), 19 S mg , significantly exceeds that of composite electrodes, indicating that the thin film approach is a promising route for achieving high performance in combination with low platinum loadings.